I'd say Death Note is a pretty good first anime choice, that's sure to get her hooked. Never seen Hetalia. Angel Beats would be a good one too, I'd think.
Anyways, finished Psycho Pass, it's great. Recommend it to anyone. It is a bit violent at times, though. Just a warning. - Edit -- By a bit violent, I mean it can get pretty gruesome at times...I tend to understate things a bit. It's not totally overkill, but still, it's kind of gory. Still definitely worth a watch. Probably one of the best shows I've seen recently.
After I finished that, someone had recommended that I watch Chihayafuru. Honestly, the concept is a bit of a strange one, but good. Still waiting for the second season to finish, but the first season was great. Really lighthearted (big change of pace from what I've been watching lately).
I also just finished the first season of Darker than Black. Not sure exactly what to think. It was okay, I guess. By the end of it I was hooked, but it definitely started off pretty slow. Not the best anime around, but I like it. Going to finish the second season before I say anything more.
Oh, and someone recommended Bakuman as well. I think I'm going to watch that next. Concept seems a bit odd, but I'll give it a shot. Seems like a long watch, so hopefully I get a few more recommendations before I finish watching it. I'm starting to have trouble choosing what to watch, lol.
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