the Community Mental Health Team (are they still called that?) would probably know of NHS provision, or, as I said, look for MIND (in the phone book or Google... or you could ask at your local library - you can always say its for your sister!) and they would know what's around and may offer support groups etc
there may be a local volunteer centre/volunteer bureau that would have lists of local non-profits, including those dealing with mental health
or if you put the region you live/nearest big town people here might know of places or some good starting points
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